| Credited cast: |
 | Ben Elton | - | Himself - Presenter |
| Rest of cast listed alphabetically: |
 | Caroline Aherne | - | Mrs. Merton |
 | Damon Albarn | - | Himself |
 | Skunk Anansie | - | Themselves - Performers |
 | Mel B | - | Herself (as Spice Girls) |
 | Zoë Ball | - | Herself - Presenter, Best British Album Award |
 | Victoria Beckham | - | Herself (as Spice Girls) |
 | The Bee Gees | - | Themselves |
 | Boyzone | - | Themselves - Nominee, Best International Group Award |
| James Dean Bradfield | - | Himself |
 | Emma Bunton | - | Herself (as Spice Girls) |
 | Melanie C | - | Herself (as Spice Girls) |
 | Naomi Campbell | - | Herself - Presenter |
 | The Chemical Brothers | - | Themselves - Nominee, Best British Dance Act Award |
 | Sheryl Crow | - | Herself |
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